Round 4: Tossup 5

Characteristic ratios can be compiled for these molecules using the rotational isomeric state model. Symmetric “Maltese cross” patterns can be observed under polarized light when these molecules form semicrystalline spherulites (-5[1])(“sfir-ROO-lites”). Solutions of these molecules are considered ideal when the Mark–Houwink exponent equals one half (10[1])and the theta condition is reached. The interaction parameter chi (“kai”) is used to (10[1])calculate free energies (-5[1])of mixing for solutions of these molecules in the Flory–Huggins model. Atactic examples of these molecules usually have lowered glass-transition temperatures. Epoxy resins are “cured” into the thermoset type of these molecules, which are alternatively formed by step-growth (10[1])or chain-growth (10[1])methods. For 10 points, name these molecules made of repeating monomers. ■END■ (10[1])

ANSWER: polymers [accept polymer solutions; accept thermosets until read; accept starch or polysaccharides; prompt on plastics or thermoplastics; prompt on macromolecules or macrostructures; prompt on saccharides; prompt on starch granules; prompt on spherulites until read; prompt on crystals or liquid crystals or crystalline state or crystal lattices until read by asking “what molecules are being crystallized?”]
<Chicago A, Chemistry> | Packet E - Chicago A, Toronto B, Brandeis B, JHU A
= Average correct buzzpoint

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